Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 18961026, compound

HRID 487955Notes

Reaction equation

HRID 487955 reaction equation
[N+]([O-])(O)=O.[N+:5]([O:8][CH2:9][CH2:10][NH2:11])([O-:7])=[O:6].[CH3:12][O:13][C:14]1[CH:19]=[CH:18][C:17]([CH:20]2[S:24][C:23](=[O:25])[NH:22][CH:21]2[C:26](O)=[O:27])=[CH:16][CH:15]=1>>[N+:5]([O:8][CH2:9][CH2:10][NH:11][C:26]([CH:21]1[CH:20]([C:17]2[CH:16]=[CH:15][C:14]([O:13][CH3:12])=[CH:19][CH:18]=2)[S:24][C:23](=[O:25])[NH:22]1)=[O:27])([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 18961071HCID 18961071, compound

Product 1

HCID 18961026HCID 18961026, compound

Procedure

A procedure similar to that described in Example 1 was repeated, but using 401 mg of N-(2-nitrooxyethyl)-amine nitrate and 500 mg of 5-(4-methoxyphenyl)-2-oxothiazolidine-4-carboxylic acid, to obtain 408 mg of the title compound as colorless crystals, melting at 142°-143° C. (after recrystallization from methylene chloride).

Workup

  1. customto obtain
  2. custom408 mg of the title compound as colorless crystals, melting at 142°-143° C. (after recrystallization from methylene chloride)

Sources & evidence

ORD record
ord-054e87f1fa684ffd9c7d33aa4164ddc1
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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