Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 10376762, compound

HRID 487970Notes

Reaction equation

HRID 487970 reaction equation
[O:1]=[C:2]1[NH:6][C@@H:5]([C:7]([OH:9])=O)[CH2:4][S:3]1.[N+]([O-])(O)=O.[N+:14]([O:17][CH2:18][CH2:19][NH2:20])([O-:16])=[O:15]>>[N+:14]([O:17][CH2:18][CH2:19][NH:20][C:7]([C@H:5]1[CH2:4][S:3][C:2](=[O:1])[NH:6]1)=[O:9])([O-:16])=[O:15]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 7075248HCID 7075248, compound

Product 1

HCID 10376762HCID 10376762, compoundYield 31.3%

Procedure

Following a procedure similar to that described in Example 1, but using 1.0 g of (4S)-2-oxothiazolidine-4-carboxylic acid and 1.15 g of N-(2-nitrooxyethyl)amine nitrate, 0.50 g of the title compound was obtained as pale yellow needles, melting at 129°-130° C. (with decomposition).

Sources & evidence

ORD record
ord-fa30d71766564f2e96d47a5648401f4b
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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