Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 54095541, compound

HRID 487971Notes

Reaction equation

HRID 487971 reaction equation
[O:1]=[C:2]1[NH:6][C@@H:5]([C:7]([OH:9])=O)[CH2:4][O:3]1.[N+]([O-])(O)=O.[N+:14]([O:17][CH2:18][CH2:19][NH2:20])([O-:16])=[O:15]>>[N+:14]([O:17][CH2:18][CH2:19][NH:20][C:7]([C@H:5]1[CH2:4][O:3][C:2](=[O:1])[NH:6]1)=[O:9])([O-:16])=[O:15]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 13052098(4R)-2-oxo-1,3-oxazolidine-4-carboxylic acid

Product 1

HCID 54095541HCID 54095541, compoundYield 41.6%

Procedure

Following a procedure similar to that described in Example 1, but using 0.23 g of (4R)-2-oxooxazolidine-4-carboxylic acid and 0.36 g of N-(2-nitrooxyethyl)amine nitrate, 0.16 g of the title compound was obtained as colorless needles, melting at 110°-112° C.

Sources & evidence

ORD record
ord-58613257b79941dc86e4b9a3495d8d26
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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