Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 54236961, compound

HRID 487972Notes

Reaction equation

HRID 487972 reaction equation
[O:1]=[C:2]1[NH:6][CH2:5][C@H:4]([C:7]([OH:9])=O)[O:3]1.[N+]([O-])(O)=O.[N+:14]([O:17][CH2:18][CH2:19][NH2:20])([O-:16])=[O:15].C1(P(N=[N+]=[N-])(C2C=CC=CC=2)=O)C=CC=CC=1>>[N+:14]([O:17][CH2:18][CH2:19][NH:20][C:7]([C@@H:4]1[O:3][C:2](=[O:1])[NH:6][CH2:5]1)=[O:9])([O-:16])=[O:15]

Participants

4

Reactant 3

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 199401P,P-Diphenylphosphinic azideHCID 18391362HCID 18391362, compound

Product 1

HCID 54236961HCID 54236961, compoundYield 20.6%

Procedure

Following a procedure similar to that described in Example 1, but using 0.32 g of (5R)-2-oxooxazolidine-5-carboxylic acid, 0.50 g of N-(2-nitrooxyethyl)amine nitrate and 0.63 ml of diphenylphosphoryl azide, 0.11 g of the title compound was obtained as pale yellow plates, melting at 103°-105° C.

Sources & evidence

ORD record
ord-f96f97517e454e0ca7c2016c5ce9770d
Source dataset
uspto-grants-1994_03
Patent number
US05298516

Reaction notes

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