Sodium Hydroxide → HCID 19091811, compound

HRID 488309Notes

Reaction equation

HRID 488309 reaction equation
[OH-].[Na+].C[O:4][C:5](=[O:35])[C:6]1[CH:11]=[C:10]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH:9]=[CH:8][C:7]=1[O:27][CH2:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>>[C:29]1([CH2:28][O:27][C:7]2[CH:8]=[CH:9][C:10]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])=[CH:11][C:6]=2[C:5]([OH:35])=[O:4])[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 53802536HCID 53802536, compound

Product 1

HCID 19091811HCID 19091811, compoundYield 94%

Procedure

Sodium hydroxide hydrolysis of 2-(phenylmethoxy)-5-(tetradecyloxy)benzoic acid methyl ester under conditions described in Example 60 gave 2-(phenylmethoxy)-5-(tetradecyloxy)benzoic acid (94% yield, mp 73°-74°).

Sources & evidence

ORD record
ord-4f6bbf0588fa4f69a7e584b57d2e0451
Source dataset
uspto-grants-1994_03
Patent number
US05298652

Reaction notes

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