HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylphosphine → HCID 69774284, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylphosphine | HCID 13831 | — |
| Reactant | Ethyl (2S)-2-ethoxy-3-(4-hydroxyphenyl)propanoate | HCID 9816147 | — |
| Reactant | HCID 22270291 | HCID 22270291 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 69774284 | HCID 69774284 | 48% |
Reaction Steps
Reaction of (Z)-3-(4-furan-2-yl-phenyl)-3-phenyl-prop-2-en-1-ol (300 mg, 1.09 mmol), tributylphosphine (0.40 ml, 1.64 mmol), (2S)-2-ethoxy-3-(4-hydroxy-phenyl)-propionic acid ethyl ester (286 mg, 1.20 mmol) and azodicarboxylic dipiperidide (413 mg, 1.64 mmol) in benzene in an identical manner to example 3 gave the title compound (260 mg, 48%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06972294B1 |
| Source dataset | uspto-grants-2005_12 |
| ORD ID | ord-15e5c14f69434c579c279a727ae644f3 |
| Source note | uspto-grants-2005_12 |