HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Chlorophenylboronic acid → 4-[4-(2-Naphthalenyl)phenyl]pyrimidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Chlorophenylboronic acid | HCID 74299 | — |
| Reactant | 4-Chloropyrimidine | HCID 642834 | — |
| Reactant | (Naphthalen-2-yl)boronic acid | HCID 2734375 | — |
| Reactant | Pyrimidine, 4-(4-chlorophenyl)- (9CI) | HCID 3301511 | — |
| Product | 4-[4-(2-Naphthalenyl)phenyl]pyrimidine | HCID 22266988 | — |
Reaction Steps
It is easy to synthesize the following compounds in the same manner as in Example 11 except that 4-(4-chlorophenyl)pyrimidine is synthesized from 4-chloropyrimidine prepared in Example 13 and 4-chlorophenylboronic acid (made by Aldrich Co.) and was reacted with 2-naphthaleneboronic acid (made by Lancaster Co.) to obtain 4-[4-(2-naphthyl)phenyl]-pyrimidine, which is used instead of 2-(benzo[b]thienyl)-5-phenylpyridine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06974639B2 |
| Source dataset | uspto-grants-2005_12 |
| ORD ID | ord-074847701ccf433a9c450bcf91b7fa06 |
| Source note | uspto-grants-2005_12 |