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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 489123Generated: October 30, 2026

Styrene → Styrene-butadiene-styrene

https://huagongshe.com/reaction/489123

Reaction equation

Participants

RoleNameHCIDCharge
ReactantStyreneHCID 7501—
Reactant1,3-ButadieneHCID 7845—
ReactantN,N,N',N'-TetramethylethylenediamineHCID 8037—
ReactantCID 53628100HCID 178418400—
SolventCyclohexaneHCID 8078—
ProductStyrene-butadiene-styreneHCID 22280236—

Reaction Steps

Styrene, butadiene and styrene were consecutively polymerized in a cyclohexane solvent in the presence of s-butyllithium and TMEDA in the same manner as in Referential Example 2, to give a styrene-butadiene-styrene block copolymer. The thus-obtained block copolymer was hydrogenated in the same manner as in Referential Example 2, to give a hydrogenated block Copolymer No. 3 (the hydrogenated block copolymer obtained in Referential Example 4 will be abbreviated as “Copolymer No. 3” hereinafter). Table 3 shows a styrene content, a number average molecular weight, a vinyl bond content and a hydrogenation ratio of the obtained Copolymer No. 3.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06977105B1
Source datasetuspto-grants-2005_12
ORD IDord-a10cc98e03f040569e844ddc88d0d4a4
Source noteuspto-grants-2005_12