Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Dimethylethylamine | HCID 11723 | — |
| Reactant | Aluminum hydride | HCID 14488 | — |
| Reactant | HCID 178506872 | HCID 178506872 | — |
| Product | AlH(CH2CH2CH2NMe2)2 | HCID 131725248 | — |
Reaction Steps
A dried flask is charged with AlH3.NEtMe2 (6.60 g, 64 mmol) under an inert atmosphere (e.g., argon) and then 50 mL of diethyl ether. The resulting slurry is cooled to −70° C. and a solution of LiCH2CH2CH2NMe2 (260 mL of 0.5 M solution in diethyl ether) is added. The resulting mixture is allowed to warm slowly to room temperature and stirred for 18 hours. The solvent is then removed in vacuo and the crude product is transferred to a smaller distillation apparatus for purification by distillation under vacuum.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06979370B2 |
|---|
| Source dataset | uspto-grants-2005_12 |
|---|
| ORD ID | ord-b14a1194f1374959a711274ee62c8030 |
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| Source note | uspto-grants-2005_12 |
|---|
