Sodium Cyanide → 2-Phenylbut-3-enenitrile

HRID 491100Notes

Reaction equation

HRID 491100 reaction equation
[CH:1]([CH:3](Cl)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:2].[C-:11]#[N:12].[Na+]>>[CH:1]([CH:3]([C:11]#[N:12])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:2]

Participants

3

Reactant 2

HCID 8929Sodium CyanideHCID 11768772Benzene, 1-(chloromethyl)-3(or 4)-ethenyl-

Product 1

HCID 147675092-Phenylbut-3-enenitrile

Procedure

a procedure according to A. Zerroukhi, A. Ainser, A. Arsac, N. Mignard, and B. Marculescu, Polymer Bulletin, 42, 535, 1999, is used. Initially, vinylbenzyl chloride is reacted with sodium cyanide to give vinylbenzyl cyanide, which is then reacted with ethanolamine to give the vinylbenzyloxazoline.

Sources & evidence

ORD record
ord-fe2faf524b034320886bde9941a28ca2
Source dataset
uspto-grants-2009_05
Patent number
US07528404B2

Reaction notes

Loading…