Potassium 1,1,2,2-tetrafluoroethanesulfonate → (3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl)-trioctylphosphonium 1,1,2,2-tetrafluoroethanesulfonate

HRID 491184Notes

Reaction equation

HRID 491184 reaction equation
[F:1][C:2]([F:10])([S:6]([O-:9])(=[O:8])=[O:7])[CH:3]([F:5])[F:4].[K+].[I-].[F:13][C:14]([F:58])([C:42]([F:57])([F:56])[C:43]([F:55])([F:54])[C:44]([F:53])([F:52])[C:45]([F:51])([F:50])[C:46]([F:49])([F:48])[F:47])[CH2:15][CH2:16][P+:17]([CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])([CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>CC(C)=O>[F:1][C:2]([F:10])([S:6]([O-:9])(=[O:8])=[O:7])[CH:3]([F:5])[F:4].[F:58][C:14]([F:13])([C:42]([F:56])([F:57])[C:43]([F:54])([F:55])[C:44]([F:52])([F:53])[C:45]([F:50])([F:51])[C:46]([F:47])([F:48])[F:49])[CH2:15][CH2:16][P+:17]([CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])([CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41]

Participants

4

Reactant 2

HCID 58905542Potassium 1,1,2,2-tetrafluoroethanesulfonateHCID 86611566(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl)trioctylphosphonium iodide

Product 1

HCID 86611564(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl)-trioctylphosphonium 1,1,2,2-tetrafluoroethanesulfonateYield 109.3%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Conditions

Temperature
60 °C

Procedure

The solvent was removed under vacuum giving (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-trioctylphosphonium iodide as a waxy solid (30.5 g). Potassium 1,1,2,2-tetrafluoroethanesulfonate (TFES-K, 13.9 g) was dissolved in reagent grade acetone (100 ml) in a separate round-bottomed flask, and to this was added (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl) -trioctylphosphonium iodide (60 g). The reaction mixture was heated at 60 degrees C. under reflux for approximately 16 hours. The reaction mixture was then filtered using a large frit glass funnel to remove the white Kl precipitate formed, and the filtrate was placed on a rotary evaporator for 4 hours to remove the acetone. The liquid was left for 24 hours at room temperature and then filtered a second time (to remove Kl) to yield the product (62 g) as shown by proton NMR.

Workup

  1. temperatureunder reflux for approximately 16 hours
  2. filtrationThe reaction mixture was then filtered
  3. customto remove the white Kl precipitate
  4. customformed
  5. customthe filtrate was placed on a rotary evaporator for 4 hours
  6. customto remove the acetone
  7. filtrationfiltered
  8. customa second time (to remove Kl)

Sources & evidence

ORD record
ord-f9eb1480a9f34a3b908d84e3abc6902d
Source dataset
uspto-grants-2009_05
Patent number
US07528287B2

Reaction notes

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