1-Bromo-4-tert-butylbenzene → Tris(4-tert-butylphenyl)sulfanium bromide

HRID 491245Notes

Reaction equation

HRID 491245 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=O)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:23]([C:27]1[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24]>O>[Br-:33].[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S+:11]([C:30]2[CH:31]=[CH:32][C:27]([C:23]([CH3:26])([CH3:25])[CH3:24])=[CH:28][CH:29]=2)[C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 775951-Bromo-4-tert-butylbenzeneHCID 184321184,4'-Sulfinylbis(tert-butylbenzene)

Product 1

HCID 23149384Tris(4-tert-butylphenyl)sulfanium bromide

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The target compound was obtained by following the procedure of Synthesis Example 1 aside from using bis(4-tert-butylphenyl) sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1, and increasing the amount of water for extraction.

Workup

  1. customThe target compound was obtained
  2. customthe procedure of Synthesis Example 1 aside
  3. customin Synthesis Example 1
  4. extractionfor extraction

Sources & evidence

ORD record
ord-560fd31e74f546fc8b41f5b8ed44b5c6
Source dataset
uspto-grants-2009_05
Patent number
US07531290B2

Reaction notes

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