HCID 53904438, compound → HCID 86585678, compound

HRID 49176Notes

Reaction equation

HRID 49176 reaction equation
COCCS(F)(F)([F:11])(CCOC)N.[F:14][C:15]1[CH:41]=[CH:40][C:18]([C:19]([C:33]2[CH:38]=[CH:37][C:36]([F:39])=[CH:35][CH:34]=2)(O)[C:20]([O:22][C@@:23]23[N:30]([CH3:31])[C@@H:27]([CH2:28][CH2:29]2)[CH2:26][CH:25]=[CH:24]3)=[O:21])=[CH:17][CH:16]=1>ClCCl>[C@@:23]12([OH:22])[N:30]([CH3:31])[C@@H:27]([CH2:28][CH2:29]1)[CH2:26][CH:25]=[CH:24]2.[F:11][C:19]([C:33]1[CH:38]=[CH:37][C:36]([F:39])=[CH:35][CH:34]=1)([C:18]1[CH:40]=[CH:41][C:15]([F:14])=[CH:16][CH:17]=1)[C:20]([O-:22])=[O:21]

Participants

4

Reactant 2

HCID 53904438HCID 53904438, compoundHCID 86585677Tropenol 4,4'-difluorobenzilate

Product 1

HCID 86585678HCID 86585678, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.94 g (0.013 mol) of bis-(2-methoxyethyl)-aminosulphur trifluoride are reacted with 3.85 g (0.01 mol) of 5d analogously to Example 4, step 4.3 in 100 ml of dichloromethane. The product is recrystallised from acetonitrile in the form of its hydrochloride.

Workup

  1. customThe product is recrystallised from acetonitrile in the form of its hydrochloride

Sources & evidence

ORD record
ord-42fc8f3633eb4fe2a0704ca5615a18c6
Source dataset
uspto-grants-2004_03
Patent number
US06706726B2

Reaction notes

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