HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Hydroxide → Pentafluorobenzenesulfonamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Ammonium Chloride | HCID 25517 | — |
| Reactant | 2,3,4,5,6-Pentafluorobenzenesulfonyl chloride | HCID 70026 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | Pentafluorobenzenesulfonamide | HCID 2063927 | — |
Reaction Steps
To an aqueous solution of ammonium chloride was added dropwise an acetone solution of pentafluorobenzenesulfonyl chloride at room temperature. During addition, pH was adjusted to 7 by an aqueous sodium hydroxide solution. Precipitated product was filtered and recrystallized from toluene to give pentafluorobenzenesulfonamide. The structure was confirmed by 1H-NMR, 19F-NMR and IR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06939646B2 |
| Source dataset | uspto-grants-2005_09 |
| ORD ID | ord-f7708f43148745cca8ced0dff432cb95 |
| Source note | uspto-grants-2005_09 |