HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 3072388, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | HCID 69796332 | HCID 69796332 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Solvent | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Product | HCID 3072388 | HCID 3072388 | 104.5% |
Reaction Steps
A solution of D6 (5.80 g, 0.018 mol) in ethanol (60 ml) and hydrazine hydrate (2 .eq., 2 ml) was heated at reflux for 1 h and cooled. The resulting precipitate was filtered and filtrate concentrated under reduced pressure to leave an oil. Chromatography on silica gel eluting with methanol in DCM (gradient elution, maximum 10%) afforded the product as an oil (3.58 g, 94%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06939891B2 |
| Source dataset | uspto-grants-2005_09 |
| ORD ID | ord-752a6dbb4a54467eb71d7614a19d7490 |
| Source note | uspto-grants-2005_09 |