Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 3-(Trichlorosilyl) Propionic Acid Benzyl Ester | HCID 54104879 | — |
| Product | HCID 53659307 | HCID 53659307 | — |
Reaction Steps
298 g (1 mole) of 3-(trichlorosilyl) propionic acid benzyl ester (I) is dissolved in 540 ml (10 mol) of nitromethane and cooled to 0° C. Added dropwise 139 ml (1 mol) of triethylamine over a period of 2 hours. The mixture is then distilled through a 22 mm×4 ft. Podbielniak column packed with Heli-pak to give 3-(dichloronitromethylsilyl) propionic acid benzyl ester (II).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06946272B1 |
|---|
| Source dataset | uspto-grants-2005_09 |
|---|
| ORD ID | ord-39c0d085d91d4f079100a40abc95dc4d |
|---|
| Source note | uspto-grants-2005_09 |
|---|
