HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750314, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | HCID 20437978 | HCID 20437978 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750314 | HCID 59750314 | 71.7% |
Reaction Steps
A mixture of methyl thiosalicylate (1.1 g, 6.4 mmol), 6-cyano-2-pyridinecarboxamide (0.47 g, 3.1 mmol), triethylamine (1.0 ml, 7.1 mmol) and toluene (3 ml) was refluxed for 6 hrs as described in Example. After cooling, the precipitated crystals were collected by filtration and recrystallized from hexane-ethanol to give the titled compound (0.63 g, 70%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07767665B2 |
| Source dataset | uspto-grants-2010_08 |
| ORD ID | ord-29f882017047426ebad4b170fc6ba4d1 |
| Source note | uspto-grants-2010_08 |