HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750311, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | HCID 22939358 | HCID 22939358 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750311 | HCID 59750311 | 13% |
Reaction Steps
A mixture of methyl thiosalicylate (0.37 g, 2.2 mmol), 2-cyano-6-(4-methylphenyl)thiopyridine (0.50 g, 2.2 mmol), triethylamine (0.46 ml, 3.3 mmol) and toluene (30 ml) was refluxed for 48 hrs as described in Example 1. The solvent was concentrated under reduced pressure. The residue was recrystallized from ethanol to give the titled compound (0.10 g, 13%) as crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07767665B2 |
| Source dataset | uspto-grants-2010_08 |
| ORD ID | ord-212b00fab943489fae2b0877552a5e09 |
| Source note | uspto-grants-2010_08 |