HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750269, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | 2-Cyano-4-methylpyridine | HCID 88739 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750269 | HCID 59750269 | 64.2% |
Reaction Steps
A mixture of methyl thiosalicylate (1.15 g, 6.8 mmol), 2-cyano-4-methylpyridine (0.81 g, 6.8 mmol), triethylamine (1.50 ml, 10.8 mmol) and toluene (2.0 ml) was refluxed for 8 hrs. After cooling, the precipitated crystals were collected by filtration and recrystallized from ethanol to give the titled compound (1.11 g, 64%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07767665B2 |
| Source dataset | uspto-grants-2010_08 |
| ORD ID | ord-d04cef05179748d99b9109b3a23c2677 |
| Source note | uspto-grants-2010_08 |