HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 59750193, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Reactant | 3-Acetylpyridine-2-carbonitrile | HCID 22939416 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 59750193 | HCID 59750193 | 39.4% |
Reaction Steps
A mixture of methyl thiosalicylate (0.51 g, 3.0 mmol), 3-acetyl-2-cyanopyridine (0.40 g, 2.7 mmol), triethylamine (0.61 ml, 4.4 mmol) and toluene (2.0 ml) was refluxed for 20 hrs. After cooling, the precipitated crystals were collected by filtration and recrystallized from acetone to give the titled compound (0.30 g, 38%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07767665B2 |
| Source dataset | uspto-grants-2010_08 |
| ORD ID | ord-13ca50de6e7f4cceba0be7e2cd07e800 |
| Source note | uspto-grants-2010_08 |