HCID 58843587, compound → HCID 58843591, compound

Participants

Reaction Steps

Manganese dioxide (740 mg) was added to a solution of (1S)-1,5-anhydro-2,3,4,6-tetra-O-benzyl-1-[3-fluoro-5-(hydroxylmethyl)phenyl]-D-glucitol (0.5 g) in chloroform (10 ml), and the mixture was stirred for 24 hours. After filtration through celite, washing with chloroform was carried out, and the filtrate was concentrated. The resulting residue was dried to obtain 3-(-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-5-fluorobenzaldehyde (0.4 g).

Provenance & Evidence