참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium borohydride | HCID 4311764 | — |
| 반응물 | Butyl(iodo)diphenylstannane | HCID 68417447 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | Butyldiphenyltin Hydride | HCID 301705 | — |
반응 단계
In a Schlenk tube, a suspension of NaBH4 (1.31 g, 34 mmol) in 50 mL of absolute ethanol was cooled at 0° C. under nitrogen. Then, a solution of BuSnPh2I (22.2 g) in ethanol was added slowly under stirring. After 3 hours at room temperature in the dark, petroleum ether was added, the solution was washed and dried over MgSO4. Solvents were eliminated under reduced pressure. A colourless oil was obtained (6.67 g, 0.02 mol).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07772417B2 |
|---|
| 출처 데이터셋 | uspto-grants-2010_08 |
|---|
| ORD ID | ord-9e083eec9433403aaadda0b61764b698 |
|---|
| 출처 메모 | uspto-grants-2010_08 |
|---|
