HRID502101

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID3548422

3-Ethynylthiophene

C6H4S

结构：CC(=O)OC[C@H]1O[C@](O)(c2ccc(Cl)c(Cc3ccc(OS(=O)(=O)C(F)(F)F)cc3)c2)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

HCID86605978

未命名化合物

PRODUCTS

生成物

结构：CC(=O)OC[C@H]1O[C@](O)(c2ccc(Cl)c(Cc3ccc(C#Cc4ccsc4)cc3)c2)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

HCID86607252

未命名化合物

PROCEDURE

实验过程

The compound was obtained starting from 1-chloro-4-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranos-1-yl)-2-(4-trifluoromethylsulfonyloxy-benzyl)-benzene and 3-ethynyl-thiophene.

WORKUP

后处理

customThe compound was obtained

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-342aa5d16c244232a73c569ca9b81be4
来源数据集: uspto-grants-2010_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07772378B2
来源说明: uspto-grants-2010_08

反应 SMILES

[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C@:8]2([O:26][C@H:25]([CH2:27][O:28][C:29](=[O:31])[CH3:30])[C@@H:20]([O:21][C:22](=[O:24])[CH3:23])[C@H:15]([O:16][C:17](=[O:19])[CH3:18])[C@H:10]2[O:11][C:12](=[O:14])[CH3:13])[OH:9])=[CH:4][C:3]=1[CH2:32][C:33]1[CH:38]=[CH:37][C:36](OS(C(F)(F)F)(=O)=O)=[CH:35][CH:34]=1.[C:47]([C:49]1[CH:53]=[CH:52][S:51][CH:50]=1)#[CH:48]>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C@:8]2([O:26][C@H:25]([CH2:27][O:28][C:29](=[O:31])[CH3:30])[C@@H:20]([O:21][C:22](=[O:24])[CH3:23])[C@H:15]([O:16][C:17](=[O:19])[CH3:18])[C@H:10]2[O:11][C:12](=[O:14])[CH3:13])[OH:9])=[CH:4][C:3]=1[CH2:32][C:33]1[CH:38]=[CH:37][C:36]([C:48]#[C:47][C:49]2[CH:53]=[CH:52][S:51][CH:50]=2)=[CH:35][CH:34]=1