HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminum hydride → HCID 86609557, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminum hydride | HCID 14487 | — |
| Reactant | Ethyl 3-ethoxy-4-iodobenzoate | HCID 23090718 | — |
| Reactant | HCID 72207183 | HCID 72207183 | — |
| Catalyst | Manganese dioxide | HCID 14801 | — |
| Product | HCID 86609557 | HCID 86609557 | — |
Reaction Steps
The necessary intermediate 4-Cyclopropyl-3-ethoxy-benzaldehyde was prepared as described in example 158, but using 3-ethoxy-4-iodo-benzaldehyde (synthesized from 3-ethoxy-4-iodo-benzoic acid ethyl ester (CAS NO. 741699-04-7) by DIBAL-H reduction followed by MnO2 oxidation) as starting material, as light brown oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07772253B2 |
| Source dataset | uspto-grants-2010_08 |
| ORD ID | ord-a750cd6e9d7447e49141bec099a82f46 |
| Source note | uspto-grants-2010_08 |