HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 50519Generated: October 25, 2026
2,4-Dinitrophenol → 1-Bromo-4-(2,4-dinitrophenyloxy)but-2-ene
https://huagongshe.com/reaction/50519
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2,4-Dinitrophenol | HCID 1493 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-Butene, 1,4-dibromo- | HCID 13180 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | 1-Bromo-4-(2,4-dinitrophenyloxy)but-2-ene | HCID 73994034 | 46.7% |
Reaction Steps
A mixture of 2,4-dinitrophenol (4.6 g, 80 wt %), potassium carbonate (4.2 g), NMP (40 mL) and 1,4-dibromo-2-butene (12.8 g) was heated to 45° C. for 2 hr. Extraction in the normal fashion and Kugelrohr distillation of the excess dibromide (0.1 mm Hg, 80° C.) gave 1-bromo-4-(2,4-dinitrophenyloxy)but-2-ene (3.7 g, mp 55-57° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06713135B2 |
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| Source dataset | uspto-grants-2004_03 |
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| ORD ID | ord-001383a7dc4048e8b945bdebc5387987 |
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| Source note | uspto-grants-2004_03 |
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