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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 50523Generated: October 30, 2026

Allyl bromide → N-allyl-N-[4-(perfluorohexyl)phenyl]-2,4-dinitrobenzenamine

https://huagongshe.com/reaction/50523

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAllyl bromideHCID 7841—
ReactantPotassium CarbonateHCID 11430—
ReactantHCID 22735010HCID 22735010—
SolventN-methyl-2-pyrrolidoneHCID 13387—
ProductN-allyl-N-[4-(perfluorohexyl)phenyl]-2,4-dinitrobenzenamineHCID 22734998—

Reaction Conditions

Temperature75 °C

Reaction Steps

A mixture of N-[4-(perfluorohexyl)phenyl]-2,4-dinitrobenzenamine (3.6 g, 6.2 mmol), NMP (40 mL), potassium carbonate (3.0 g) and allyl bromide (0.65 mL) was stirred at 75° C. for 4 hr. The mixture was extracted in the normal fashion, and the product recrystallized to give N-allyl-N-[4-(perfluorohexyl)phenyl]-2,4-dinitrobenzenamine (2.9 g).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06713135B2
Source datasetuspto-grants-2004_03
ORD IDord-434ba6325e9d483294ed93a19cb9365f
Source noteuspto-grants-2004_03