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HRID50709

反应详情

EQUATION

反应方程式

HRID 50709 的结构方程式

REACTANTS

反应物

2
结构：Cc1cc(Br)cc(Br)c1
HCID15361

Benzene, 1,3-dibromo-5-methyl-

C7H6Br2

结构：CC1(C)OC(=O)Nc2ccc(B(O)O)cc21
HCID10987806

(4,4-Dimethyl-2-oxo-1,4-dihydro-2H-3,1-benzoxazin-6-yl)boronic acid

C10H12BNO4

PRODUCTS

生成物

1
结构：Cc1cc(Br)cc(-c2ccc3c(c2)C(C)(C)OC(=O)N3)c1
HCID9924311

未命名化合物

PROCEDURE

实验过程

Prepared from (4,4-dimethyl-1,4-dihydro-2-oxo-2H-3,1-benzoxazin-6-yl)boronic acid and 3,5-dibromotoluene according to Procedure B. White solid: mp 231-233° C.; 1H-NMR (DMSO-d6) δ 10.4 (s, 1H), 7.66 (s, 1H), 7.58-7.56 (m, 2H), 7.50 (s, 1H), 7.37 (s, 1H), 6.95 (d, 1H, J=8.67 Hz), 2.37 (s, 3H), 1.67 (s, 6H); (ESI) m/z 344/346 ([M−H]−, 100%); Anal. Calc. For C17H16BrNO2: C, 58.98; H, 4.66, N, 4.05. Found: C, 58.82; H, 4.62; N, 3.94.