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HRID50710

反应详情

EQUATION

反应方程式

HRID 50710 的结构方程式

REACTANTS

反应物

2
结构：FC(F)(F)Oc1cc(Br)cc(Br)c1
HCID2761179

1,3-Dibromo-5-(trifluoromethoxy)benzene

C7H3Br2F3O

结构：CC1(C)OC(=O)Nc2ccc(B(O)O)cc21
HCID10987806

(4,4-Dimethyl-2-oxo-1,4-dihydro-2H-3,1-benzoxazin-6-yl)boronic acid

C10H12BNO4

PRODUCTS

生成物

1
结构：CC1(C)OC(=O)Nc2ccc(-c3cc(Br)cc(OC(F)(F)F)c3)cc21
HCID10273358

未命名化合物

PROCEDURE

实验过程

Prepared from (4,4-dimethyl-1,4-dihydro-2-oxo-2H-3,1-benzoxazin-6-yl)boronic acid and 1,3-dibromo-5-trifluoromethoxybenzene according to Procedure B. White solid: mp 214-216° C.; 1H-NMR (DMSO-d6) δ 10.4 (s, 1H), 7.99 (s, 1H), 7.73 (s, 1H), 7.68-7.62 (m, 3H), 6.97 (d, 1H, J=8.0 Hz), 1.68 (s, 6H); MS (ESI) m/z 414 ([M−H]−, 100%), Anal. Calc. For C17H13BrF3NO3: C, 49.06; H, 3.15; N, 3.37. Found: C, 49.16; H, 3.05; N, 3.30.