HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl chloride → (3-Chloropropyl)(triethyl)silane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | Triethylsilane | HCID 12052 | — |
| Catalyst | Cupric acetate | HCID 8895 | — |
| Catalyst | Copper | HCID 23978 | — |
| Catalyst | Cupric Chloride | HCID 24014 | — |
| Catalyst | Copper Sulfate | HCID 24462 | — |
| Product | (3-Chloropropyl)(triethyl)silane | HCID 12566784 | — |
Reaction Steps
Table 1 shows that copper catalysts, especially copper chloride and copper acetate, and copper sulphate, are effective in catalyzing the hydrosilation of allyl chloride with triethylsilane, at 200° C. for 45 hours, yielding quantitatively 3-chloropropyltriethylsilane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06713644B1 |
| Source dataset | uspto-grants-2004_03 |
| ORD ID | ord-0c899d160f574f5793f8830562413118 |
| Source note | uspto-grants-2004_03 |