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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 51238Generated: October 26, 2026

Allyl chloride → (3-Chloropropyl)(triethyl)silane

https://huagongshe.com/reaction/51238

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAllyl chlorideHCID 7850—
ReactantTriethylsilaneHCID 12052—
CatalystCupric acetateHCID 8895—
CatalystCopperHCID 23978—
CatalystCupric ChlorideHCID 24014—
CatalystCopper SulfateHCID 24462—
Product(3-Chloropropyl)(triethyl)silaneHCID 12566784—

Reaction Steps

Table 1 shows that copper catalysts, especially copper chloride and copper acetate, and copper sulphate, are effective in catalyzing the hydrosilation of allyl chloride with triethylsilane, at 200° C. for 45 hours, yielding quantitatively 3-chloropropyltriethylsilane.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06713644B1
Source datasetuspto-grants-2004_03
ORD IDord-0c899d160f574f5793f8830562413118
Source noteuspto-grants-2004_03