HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Carbonate → 9-(4-Bromo-2-nitrophenyl)phenanthrene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | 1,4-Dibromo-2-nitrobenzene | HCID 77004 | — |
| Reactant | 9-Phenanthracenylboronic acid | HCID 11775704 | — |
| Catalyst | HCID 178418397 | HCID 178418397 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 9-(4-Bromo-2-nitrophenyl)phenanthrene | HCID 86669971 | — |
Reaction Steps
A 500 mL round bottom flask was charged with toluene (250 mL), phenanthracene-9-boronic acid (18.2 g, 82 mmol), 2,5-dibromonitrobenzene (23.1 g, 82.3 mmol), Pd(PPh3)4 (2.8 g, 2.5 mmol), and 2M Na2CO3 aqueous solution (124 mL).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09102616B2 |
| Source dataset | uspto-grants-2015_08 |
| ORD ID | ord-ca3140e8006f486a8305514f6a242292 |
| Source note | uspto-grants-2015_08 |