化工社化工社 化学情報印刷レポート · 研究参考用
Tetrahydrofuran → 5-(6-bromonaphthalen-2-yl)-N1,N3-bis(4-methoxyphenyl)-N1,N3-diphenylbenzene-1,3-Diamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tetrahydrofuran | HCID 8028 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 2,6-Dibromonaphthalene | HCID 640591 | — |
| 反応物 | N1,N3-bis(4-methoxyphenyl)-N1,N3-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene-1,3-diamine | HCID 68193967 | — |
| 触媒 | HCID 178418397 | HCID 178418397 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 5-(6-bromonaphthalen-2-yl)-N1,N3-bis(4-methoxyphenyl)-N1,N3-diphenylbenzene-1,3-Diamine | HCID 68193747 | — |
反応手順
13.42 g of a product (yield: 66%) was obtained in the same manner as described in the synthesis method of intermediate 2-3 except that N1,N3-bis(4-methoxyphenyl)-N1,N3-diphenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene-1,3-diamine (17.76 g, 30 mmol), 2,6-dibromonaphthalene (9.44 g, 33 mmol), Pd(PPh3)4 (1.04 g, 0.9 mmol), K2CO3 (12.44 g, 90 mmol), THF (90 mL), and water (45 mL) were used.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09102616B2 |
| 出典データセット | uspto-grants-2015_08 |
| ORD ID | ord-17559f20e43e4b8f8c2a43fb252975b4 |
| 出典メモ | uspto-grants-2015_08 |