HCID 86702672, compound → HCID 86702671, compound

HRID 513338Notes

Reaction equation

HRID 513338 reaction equation
[C:1]1(/[CH:7]=[CH:8]/[CH2:9][CH2:10][CH2:11][CH2:12][C:13]#[C:14][C:15](=[O:17])[CH3:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>ClC1C=CC=CC=1Cl>[CH2:5]1[C:6]2[C:1](=[CH:7][C:8]3[C:13]([C:14]=2[C:15](=[O:17])[CH3:16])=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH2:2][CH2:3][CH2:4]1

Participants

3

Reactant 1

HCID 86702672HCID 86702672, compound

Product 1

HCID 86702671HCID 86702671, compound

Reagents, catalysts & solvents 1

HCID 72391,2-DichlorobenzeneSolvent

Conditions

Temperature
300 °C

Procedure

To a 10 mL microwave irradiation vial equipped with a stir bar was added enyne 5l (0.042 g, 0.19 mmol) in o-dichlorobenzene (3.1 mL). The reaction was irradiated with stirring at 300° C. for 50 min in an Anton Parr Monowave 300 microwave reactor until complete by TLC. The reaction turned light brown in color. The reaction was then transferred to a vial and concentrated under high vacuum to yield naphthalene 6l as a brown oil (0.044 g, quant.).

Workup

  1. customTo a 10 mL microwave irradiation
  2. customvial equipped with a stir bar
  3. customThe reaction was irradiated
  4. concentrationconcentrated under high vacuum

Sources & evidence

ORD record
ord-629dad76a8064a71900d19149a6b4d9f
Source dataset
uspto-grants-2015_08
Patent number
US09102703B2

Reaction notes

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