HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Ethyl-3-methylcyclopentanone → 3-Ethyl-3-methyl-1-vinylcyclopentanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Ethyl-3-methylcyclopentanone | HCID 21718634 | — |
| Reactant | HCID 178418507 | HCID 178418507 | — |
| Product | 3-Ethyl-3-methyl-1-vinylcyclopentanol | HCID 89428906 | 60% |
Reaction Steps
3-Ethyl-3-methylcyclopentanone (2b, 30.0 g, 0.24 mol) was reacted with vinylmagnesium bromide (0.6M in THF, 285 ml, 0.29 mol), as described in Example 1b, to afford 3b (22.0 g, 2:1 mixture of diastereomers, 60% yield) as a colorless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09109186B2 |
| Source dataset | uspto-grants-2015_08 |
| ORD ID | ord-1292d29f1d55408786b1e4c6a4b314be |
| Source note | uspto-grants-2015_08 |