Sodium Hydroxide → HCID 71496026, compound

HRID 516890Notes

Reaction equation

HRID 516890 reaction equation
[OH-:1].[Na+:2].[O:3]1[CH2:8][CH2:7][CH:6]([C:9]2[C:10](=[O:21])[O:11][C:12](=[O:20])[C:13]=2[CH:14]2[CH2:19][CH2:18][O:17][CH2:16][CH2:15]2)[CH2:5][CH2:4]1>O1CCOCC1>[O:3]1[CH2:8][CH2:7][CH:6](/[C:9](=[C:13](\[CH:14]2[CH2:19][CH2:18][O:17][CH2:16][CH2:15]2)/[C:12]([O-:11])=[O:20])/[C:10]([O-:21])=[O:1])[CH2:5][CH2:4]1.[Na+:2].[Na+:2]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 90184986HCID 90184986, compound

Product 1

HCID 71496026HCID 71496026, compoundYield 94.8%

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

A 1 M NaOH (4.5 ml, 4.5 mmol) was added to a solution of 3,4-bis(tetrahydro-2H-pyran-4-yl)furan-2,5-dione (600 mg, 2.25 mmol) in 1,4-dioxane (4.5 ml) at room temperature, and the mixture was stirred for 24 hr. The reaction mixture was concentrated, and the residue was dried in vacuo to give the title compound as a colorless solid (0.7 g, quantitative).

Workup

  1. concentrationThe reaction mixture was concentrated
  2. customthe residue was dried in vacuo

Sources & evidence

ORD record
ord-a366e05f81f24d648f7cb17ab7ffed20
Source dataset
uspto-grants-2015_08
Patent number
US09115079B2

Reaction notes

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