3-Chloro-2-methyl-1-propene → HCID 125476811, compound
Reaction equation
Br[CH2:2][CH:3]=[CH:4][CH3:5].C(Cl)[C:7](=[CH2:9])[CH3:8]>>[CH3:5]/[CH:4]=[CH:3]/[CH2:2][C:2]#[C:3][CH2:4][CH2:5][CH2:8][CH2:7][CH3:9]Participants
3
Procedure
Obtained in 74% yield (as a 92:8 E/Z mixture) from 1-heptyn using 1-bromo-but-2-en and using methallylchloride according to the procedure described under a).
Sources & evidence
- ORD record
- ord-140ef20f4b1941b28ad92ef3470d3e95
- Source dataset
- uspto-grants-2015_08
- Patent number
- US09115329B2
Reaction notes
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