huagongshe.com
HRID521840

反应详情

EQUATION

反应方程式

HRID 521840 的结构方程式

REACTANTS

反应物

2
结构：CC1CC(=O)CCC(c2c([N+](=O)[O-])cnn2C)O1
HCID86713774

未命名化合物

结构：CCC1CC(NS(=O)C(C)(C)C)CCC(c2c([N+](=O)[O-])cnn2C)O1
HCID86713781

未命名化合物

PRODUCTS

生成物

1
结构：CC1CC(NS(=O)C(C)(C)C)CCC(c2c([N+](=O)[O-])cnn2C)O1
HCID86713782

未命名化合物

PROCEDURE

实验过程

Following the procedure for Intermediate 13 starting from 2-methyl-7-(2-methyl-4-nitro-pyrazol-3-yl)oxepan-4-one gave N-(2-methyl-7-(2-methyl-4-nitro-pyrazol-3-yl)oxepan-4-yl)-2-methyl-propane-2-sulfinamide as an off-white solid (208 mg, 40% over two steps). 1H NMR (400 MHz, CDCl3) δ 8.01 (s, 1H), 5.63-5.51 (m, 1H), 4.05 (s, 3H), 3.86-3.72 (m, 2H), 3.19-3.11 (m, 1H), 2.22-1.69 (m, 6H), 1.29-1.20 (m, 12H).