HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetamide → HCID 605997, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetamide | HCID 178 | — |
| Reactant | N,N'-Dimethylethylenediamine | HCID 8070 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Silane, (4-bromophenyl)trimethyl- | HCID 138897 | — |
| Catalyst | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | HCID 605997 | HCID 605997 | — |
Reaction Steps
Under a flow of argon, in a 1 L-recovery flask, 35 g of 1-bromo-4-(trimethylsilyl)benzene, 22.6 g of acetamide, 5.8 g of copper(I)iodide, 42.2 g of potassium carbonate, and 380 mL of xylene were placed. After stirring, 6.6 mL of N,N′-dimethylethylenediamine was added. The resultant was heated and stirred at reflux for 18 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09331285B2 |
| Source dataset | uspto-grants-2016_05 |
| ORD ID | ord-f2e389c221644e33b613cad9ed947951 |
| Source note | uspto-grants-2016_05 |