HCID 20719184, compound → HCID 86732653, compound

HRID 523331Notes

Reaction equation

HRID 523331 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:41]=[C:42]([N+:44]([O-])=O)[CH:43]=1)[C:7]([O:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17](=[O:40])/[CH:18]=[CH:19]/[C:20]1[CH:25]=[CH:24][C:23]([O:26][C:27](=[O:39])[C:28]2[CH:33]=[CH:32][C:31]([O:34][CH2:35][CH2:36][O:37][CH3:38])=[CH:30][CH:29]=2)=[CH:22][CH:21]=1)=[O:8])([O-])=O.NC1C=C(C=C(N)C=1)C(OCCCCCCOC1C=CC(/C=C/C(OC)=O)=CC=1OC)=O>>[NH2:1][C:4]1[CH:5]=[C:6]([CH:41]=[C:42]([NH2:44])[CH:43]=1)[C:7]([O:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17](=[O:40])/[CH:18]=[CH:19]/[C:20]1[CH:25]=[CH:24][C:23]([O:26][C:27](=[O:39])[C:28]2[CH:29]=[CH:30][C:31]([O:34][CH2:35][CH2:36][O:37][CH3:38])=[CH:32][CH:33]=2)=[CH:22][CH:21]=1)=[O:8]

Participants

3

Reactant 2

HCID 20719184HCID 20719184, compoundHCID 89495661HCID 89495661, compound

Product 1

HCID 86732653HCID 86732653, compound

Procedure

6-{[(2E)-3-(4-{[4-(2-methoxyethoxy)benzoyl]oxy}phenyl)prop-2-enoyl]oxy}hexyl 3,5-diaminobenzoate is prepared from 6-{[(2E)-3-(4-{[4-(2-methoxyethoxy)benzoyl]oxy}phenyl)prop-2-enoyl]oxy}hexyl 3,5-dinitrobenzoate analogous to 6-{2-methoxy-4-[(1E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}hexyl 3,5-diaminobenzoate (Example 1)

Sources & evidence

ORD record
ord-3ca79d8a2567453784f5fa9934ce2bb8
Source dataset
uspto-grants-2016_05
Patent number
US09334366B2

Reaction notes

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