huagongshe.com
HRID526675

反应详情

EQUATION

反应方程式

HRID 526675 的结构方程式

REACTANTS

反应物

4
反应SMILES：CC(=O)O[C@H]1Cc2ccccc2N(C(N)=O)c2ccccc21
HCID179344

Eslicarbazepine acetate

C17H16N2O3

反应SMILES：NC(=O)N1c2ccccc2C[C@@H](O)c2ccccc21
HCID9816485

R-Licarbazepine

C15H14N2O2

反应SMILES：NC(=O)N1c2ccccc2C[C@H](O)c2ccccc21
HCID9881504

Eslicarbazepine

C15H14N2O2

反应SMILES：CC(=O)O[C@@H]1Cc2ccccc2N(C(N)=O)c2ccccc21
HCID10590023

未命名化合物

PRODUCTS

产物

1
反应SMILES：NC(=O)N1c2ccccc2CC(=O)c2ccccc21
HCID34312

Oxcarbazepine

C15H12N2O2

PROCEDURE

实验过程

In an another embodiment, the invention provides a process for preparing (S)-(−)-10-acetoxy-10,11-dihydro-5H-dibenz[b,f]azepine-5-carboxamide, or (R)-(+)-10-acetoxy-10,11-dihydro-5H-dibenz[b,f]azepine-5-carboxamide from (S)-(+)-10,11-dihydro-10-hydroxy-5H-dibenz[b,f]azepine-5-carboxamide or (R)-(−)-10,11-dihydro-10-hydroxy-5H-dibenz[b,f]azepine-5-carboxamide, which are obtained by enantioselective reduction of 10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxamide or derivatives thereof in presence of sodium borohydride and tartaric acid derived ester of phenyl boronic acid.

WORKUP

后处理

  1. customIn an another embodiment, the invention provides a process