Cesium carbonate → HCID 89429084, compound

Participants

Reaction Steps

This compound was synthesized as a yellowish amorphous solid from 13 (114.4 mg, 0.30 mmol), 3p (130.4 mg, 0.36 mmol), and Cs2CO3 (146.6 mg, 0.45 mmol) in 62% yield by following general procedure 1.2: 1H NMR (400 MHz, CDCl3, δH) 7.61 (s, 1H), 7.41 (d, J=9.0 Hz, 2H), 7.08-6.93 (m, 6H), 5.13 (s, 2H), 3.85 (t, J=7.1 Hz, 2H), 3.48 (s, 3H), 3.41-3.33 (m, 4H), 3.31-3.22 (m, 6H), 1.88-1.74 (m, 2H), 1.61 (dt, J=14.0, 7.0 Hz, 2H), 1.52-1.35 (m, 4H). ESI-MS: 507.3 (M+H+), 529.3 (M+Na+).

Provenance & Evidence