HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → Benzoic acid, 3,5-bis(1,1-dimethylethyl)-2-nitro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 3,5-Bis(tert-butyl)benzoic acid | HCID 85339 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Benzoic acid, 3,5-bis(1,1-dimethylethyl)-2-nitro- | HCID 12291777 | — |
| Product | HCID 19963919 | HCID 19963919 | — |
Reaction Steps
3,5-Di-t-butyl-2-nitrobenzoyl chloride was prepared by nitration of 3,5-di-t-butylbenzoic acid 46.86 grams (0.20 mol) with 90% nitric acid (150 ml, d=1.5) to give 3,5-di-t-butyl-2-nitrobenzoic acid (54.6 grams) followedby treatment with thionyl chloride (250 ml) with dimethylformamide (1 ml).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05616797 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-1b0b73807bcb47e7ad054cd94bc82b55 |
| Source note | uspto-grants-1997_04 |