HRID528545

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=S(=O)(Cl)c1ccc2c(c1)OCCN2c1ccc(C(F)(F)F)cc1Br

HCID89761850

未命名化合物

结构：O=S(=O)(Oc1c(F)c(F)c(F)c(F)c1F)c1ccc2c(c1)OCCN2c1ccc(C(F)(F)F)cc1Cl

HCID89761892

未命名化合物

PRODUCTS

生成物

结构：O=S(=O)(Oc1c(F)c(F)c(F)c(F)c1F)c1ccc2c(c1)OCCN2c1ccc(C(F)(F)F)cc1Br

HCID89761935

未命名化合物

PROCEDURE

实验过程

Perfluorophenyl 4-(2-bromo-4-(trifluoromethyl)phenyl)-3,4-dihydro-2H-benzo[b][1,4]oxazine-7-sulfonate was prepared from INTERMEDIATE C according to the procedure used to prepare INTERMEDIATE F. MS (ESI, positive) m/z: 625.8 (M+Na).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-af89dbf0860848f69e2dc1d0c8ac38ea
来源数据集: uspto-grants-2016_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09346798B2
来源说明: uspto-grants-2016_05

反应 SMILES

[Br:1]C1C=C(C(F)(F)F)C=CC=1N1CCOC2C=C(S(Cl)(=O)=O)C=CC1=2.Cl[C:27]1[CH:32]=[C:31]([C:33]([F:36])([F:35])[F:34])[CH:30]=[CH:29][C:28]=1[N:37]1[CH2:42][CH2:41][O:40][C:39]2[CH:43]=[C:44]([S:47]([O:50][C:51]3[C:56]([F:57])=[C:55]([F:58])[C:54]([F:59])=[C:53]([F:60])[C:52]=3[F:61])(=[O:49])=[O:48])[CH:45]=[CH:46][C:38]1=2>>[Br:1][C:27]1[CH:32]=[C:31]([C:33]([F:36])([F:35])[F:34])[CH:30]=[CH:29][C:28]=1[N:37]1[CH2:42][CH2:41][O:40][C:39]2[CH:43]=[C:44]([S:47]([O:50][C:51]3[C:56]([F:57])=[C:55]([F:58])[C:54]([F:59])=[C:53]([F:60])[C:52]=3[F:61])(=[O:49])=[O:48])[CH:45]=[CH:46][C:38]1=2