HuagongsheHuagongshe Chemistry Print Report · For research reference only
L-Malic Acid → HCID 13963152, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | L-Malic Acid | HCID 222656 | — |
| Reactant | (R)-3-(tert-butyldimethylsilyloxy)-4-chlorobutanal | HCID 13963153 | — |
| Product | HCID 13963152 | HCID 13963152 | — |
Reaction Steps
(S)-3-(tert-Butyldimethylsilyloxy)-4-chlorobutanal was prepared by the same route as (R)-3-(tert-butyldimethylsilyloxy)-4-chlorobutanal starting from (S)-2-hydroxysuccinic acid. 1H NMR (400 MHz, CDCl3) δ 9.72 (dd, J=1.6, 2.2 Hz, 1H), 4.33-4.28 (m, 1H), 3.46 (dd, J=4.7, 11.1 Hz, 1H), 3.39 (dd, J=6.4, 11.1 Hz, 1H), 2.68 (dd, J=1.5, 4.7 Hz, 1H), 2.62 (dd, J=2.3, 6.8 Hz, 1H), 0.79 (s, 9H), 0.04 (s, 3H), 0.01 (s, 3H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09351962B2 |
| Source dataset | uspto-grants-2016_05 |
| ORD ID | ord-b1bbd95678d8433baa953c07941e4f98 |
| Source note | uspto-grants-2016_05 |