HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-chloro-2-N,4-N-dipropyl-1,3,5-triazine-2,4-diamine → N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-hydroxylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-chloro-2-N,4-N-dipropyl-1,3,5-triazine-2,4-diamine | HCID 18304 | — |
| Reactant | Hydroxyamine hydrochloride | HCID 443297 | — |
| Product | N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-hydroxylamine | HCID 57377803 | — |
Reaction Steps
N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-hydroxylamine (XLV) was prepared from 2-chloro-N-(4,6-bis-(n-propylamino)-[1,3,5]triazine (XXXIV) and hydroxylamine hydrochloride as described in Example 13 (99% yield). 400 MHz 1H NMR (DMSO-d6, ppm) 9.0-8.6 (1H, br s), 8.39-8.14 (1H, s), 6.89-6.55 (2H, m), 3.23-3.06 (4H, m), 1.54-1.40 (4H, m), 0.84 (6H, t, J=7.4 Hz). ESI-MS (m/z): 227 [M+H]+. MP: 138-141° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09351972B2 |
| Source dataset | uspto-grants-2016_05 |
| ORD ID | ord-8ea95c42582b4459bc55aeb749f91166 |
| Source note | uspto-grants-2016_05 |