HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-chloro-2-N,4-N-dipropyl-1,3,5-triazine-2,4-diamine → N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-N-methyl-hydroxylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-chloro-2-N,4-N-dipropyl-1,3,5-triazine-2,4-diamine | HCID 18304 | — |
| Reactant | N-methylhydroxylamine hydrochloride | HCID 77906 | — |
| Product | N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-N-methyl-hydroxylamine | HCID 57377805 | — |
Reaction Steps
N-(4,6-Bis-propylamino-[1,3,5]triazin-2-yl)-N-methyl-hydroxylamine (XLVIII) was prepared from 2-chloro-N-(4,6-bis-(n-propylamino)-[1,3,5]triazine (XXXIV) and N-methyl-hydroxylamine hydrochloride as described in Example 13 (90% yield). 400 MHz 1H NMR (DMSO-d6, ppm) 8.93 (1H, s), 6.92-6.43 (2H, m), 3.23-3.07 (7H, m), 1.55-1.38 (4H, m), 0.84 (6H, t, J=7.4 Hz). ESI-MS (m/z) 241 [M+H]+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09351972B2 |
| Source dataset | uspto-grants-2016_05 |
| ORD ID | ord-b5c30b393ef74b3ca23b57ac7a73670b |
| Source note | uspto-grants-2016_05 |