HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromotrimethylsilane → 1-Naphthylthiomethanediphosphonic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromotrimethylsilane | HCID 76113 | — |
| Reactant | Tetraethyl 1-naphthylthiomethanediphosphonate | HCID 86750679 | — |
| Product | 1-Naphthylthiomethanediphosphonic Acid | HCID 86750678 | 82.1% |
Reaction Steps
Following the same method as described in Example 2, 6.70 g (15 mmol) of tetraethyl 1-naphthylthiomethanediphosphonate was treated with trimethylsilyl bromide, and then hydrolyzed to obtain 3.92 g of the title compound as white crystals. The yield was 78%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05618804 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-cdd3d03ae0d94a3fa8f2533a66a33143 |
| Source note | uspto-grants-1997_04 |