HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Naphthol-8-methanol → 1-Hydroxy-8-methylnaphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Naphthol-8-methanol | HCID 12203796 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium hydroxide | HCID 9942167 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1-Hydroxy-8-methylnaphthalene | HCID 12203793 | — |
Reaction Steps
Prepared from the known (J. Chem. Soc., C, (1966) 523) 8-hydroxymethyl-1-naphthol by hydrogenolysis using 0.1 equiv. of 20 % palladium hydroxide on carbon (Pearlmann's catalyst) in ethanol at 45 psi hydrogen for 4 hours in quantitative yield, M.P. 56°-59° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05618811 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-18455d351e4b4dd98317e9b68af71b6d |
| Source note | uspto-grants-1997_04 |