HRID53300

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7369

Benzenesulfonyl chloride

C6H5ClO2S

结构：Cc1cc(C)c(COc2cccc3c2C(=O)c2c(Cl)ccc4c2c-3nn4CCO)c(C)c1

HCID10863243

未命名化合物

结构：Cc1cc(C)c(COc2cccc3c2-c2nn(CCO)c4ccc(Cl)c(c24)C3=O)c(C)c1

HCID10863244

未命名化合物

PRODUCTS

生成物

结构：Cc1cc(C)c(COc2cccc3c2C(=O)c2c(Cl)ccc4c2c-3nn4CCOS(=O)(=O)c2ccccc2)c(C)c1

HCID86750691

未命名化合物

PROCEDURE

实验过程

Starting with benzenesulfonyl chloride and the mixture of regioisomers of 5-chloro-2-(2-hydroxyethyl)-7-[(2,4,6-trimethylphenyl)methoxy]anthra-[1,9-cd]pyrazol-6(2H)-one II and 5-chloro-2-(2-hydroxyethyl)-10-[(2,4,6-trimethylphenyl) methoxy]anthra-[1,9-cd]pyrazol-6(2H)-one III, using the procedure of example 3, the title compound was prepared.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2cfee49587a7491f9b68ddf95299674a
来源数据集: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05618944
来源说明: uspto-grants-1997_04

反应 SMILES

[C:1]1([S:7](Cl)(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:11][C:12]1[CH:13]=[CH:14][C:15]2[N:16]([CH2:40][CH2:41][OH:42])[N:17]=[C:18]3[C:27]4[C:22](=[C:23]([O:28][CH2:29][C:30]5[C:35]([CH3:36])=[CH:34][C:33]([CH3:37])=[CH:32][C:31]=5[CH3:38])[CH:24]=[CH:25][CH:26]=4)[C:21](=[O:39])[C:20]=1[C:19]=23.ClC1C=CC2N(CCO)N=C3C4C(=CC=CC=4OCC4C(C)=CC(C)=CC=4C)C(=O)C=1C=23>>[Cl:11][C:12]1[CH:13]=[CH:14][C:15]2[N:16]([CH2:40][CH2:41][O:42][S:7]([C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)(=[O:9])=[O:8])[N:17]=[C:18]3[C:27]4[C:22](=[C:23]([O:28][CH2:29][C:30]5[C:35]([CH3:36])=[CH:34][C:33]([CH3:37])=[CH:32][C:31]=5[CH3:38])[CH:24]=[CH:25][CH:26]=4)[C:21](=[O:39])[C:20]=1[C:19]=23