HRID53301

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID31297

Methanesulfonyl chloride

CH3ClO2S

结构：Cc1cc(C)c(COc2cccc3c2C(=O)c2c(Cl)ccc4c2c-3nn4CCO)c(C)c1

HCID10863243

未命名化合物

结构：Cc1cc(C)c(COc2cccc3c2-c2nn(CCO)c4ccc(Cl)c(c24)C3=O)c(C)c1

HCID10863244

未命名化合物

PRODUCTS

生成物

结构：Cc1cc(C)c(COc2cccc3c2C(=O)c2c(Cl)ccc4c2c-3nn4CCOS(C)(=O)=O)c(C)c1

HCID15232220

未命名化合物

PROCEDURE

实验过程

Starting with methanesulfonyl chloride and the mixture of regioisomers of 5-chloro-2-(2-hydroxyethyl)-7-[(2,4,6-trimethylphenyl)methoxy]anthra-[1,9cd]pyrazol-6-(2H)-one II and 5-chloro-2-(2-hydroxyethyl)-10-[(2,4,6-trimethylphenyl) methoxy]anthra-[1,9-cd]pyrazol-6(2H)-one III, usiong the procedure of example 3, the title compound was prepared.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-154881ec22894a5c8b2a4e7da3734674
来源数据集: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05618944
来源说明: uspto-grants-1997_04

反应 SMILES

[CH3:1][S:2](Cl)(=[O:4])=[O:3].[Cl:6][C:7]1[CH:8]=[CH:9][C:10]2[N:11]([CH2:35][CH2:36][OH:37])[N:12]=[C:13]3[C:22]4[C:17](=[C:18]([O:23][CH2:24][C:25]5[C:30]([CH3:31])=[CH:29][C:28]([CH3:32])=[CH:27][C:26]=5[CH3:33])[CH:19]=[CH:20][CH:21]=4)[C:16](=[O:34])[C:15]=1[C:14]=23.ClC1C=CC2N(CCO)N=C3C4C(=CC=CC=4OCC4C(C)=CC(C)=CC=4C)C(=O)C=1C=23>>[Cl:6][C:7]1[CH:8]=[CH:9][C:10]2[N:11]([CH2:35][CH2:36][O:37][S:2]([CH3:1])(=[O:4])=[O:3])[N:12]=[C:13]3[C:22]4[C:17](=[C:18]([O:23][CH2:24][C:25]5[C:30]([CH3:31])=[CH:29][C:28]([CH3:32])=[CH:27][C:26]=5[CH3:33])[CH:19]=[CH:20][CH:21]=4)[C:16](=[O:34])[C:15]=1[C:14]=23