HRID535543

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC1(C)[C@H]2CC[C@@H](CC(=O)O)[C@@H]1C2

HCID67161116

未命名化合物

结构：CC(C)(C)OC(=O)NCc1nn(N)c(=O)c2ccccc12

HCID131731940

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)NCc1nn(NC(=O)C[C@@H]2CC[C@H]3C[C@@H]2C3(C)C)c(=O)c2ccccc12

HCID131731942

未命名化合物

PROCEDURE

实验过程

The product of Example 41B and 2-[(1S,2S,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]acetic acid (Eigenmann, G. W.; Arnold, R. T. JACS 1959, 81, 3440-2) were treated using a method similar to that described in Example 56 to give the title compound. 1H NMR (300 MHz, DMSO-d6) δ 11.24 (s, 1H), 8.36-8.28 (m, 1H), 8.10 (d, J=7.8, 1H), 7.98 (dd, J=11.1, 4.1, 1H), 7.90 (t, J=7.1, 1H), 7.40 (s, 1H), 4.45 (d, J=5.7, 2H), 2.41-2.29 (m, 3H), 2.07-1.80 (m, 5H), 1.64-1.47 (m, 1H), 1.43-1.29 (m, 10H), 1.21 (s, 3H), 1.07 (s, 3H), 0.91 (d, J=9.5, 1H). MS (ESI+) M/Z 472 (M+NH4)+.